Cyanuric acid — friend or foe?

Clear Comfort
By Nick Rancis, Chief Water Officer, Clear Comfort
Monday, 09 May, 2016



Cyanuric acid — friend or foe?

A common pool service household name, cyanuric acid is now in the toolbox of most residential and commercial pool service professionals who are servicing outdoor pools.

Since its invention in 1829, it has been revered as invaluable and essential to keeping chlorinated pools clean and sanitary. At the same time it is labelled as misused, controversial and dangerous. To illustrate this contradiction, some health inspectors insist on the use of cyanuric acid and some health inspectors restrict its presence in public pools. How can this be the case among so many experts? Let’s take a deeper dive into the benefits and misconceptions of cyanuric acid.

Cyanuric acid, as its name suggests, is an ‘acid’. Like many commercially available acids, it is sold as a white crystalline powder, is able to easily dissolve in water and has little overall effect on other pool chemicals, such as pH, alkalinity and dissolved solids. Unlike other ‘acids’, it is commonly referred to as a chlorine stabiliser or conditioner, forming a weak and temporary chemical bond with chlorine. This means it will chemically hold onto free chlorine in the water, slow down overall oxidation reaction rates and most importantly, protect chlorine from the sun’s UV rays until the chlorine is consumed for oxidation or disinfection of material in the pool.

The primary benefit of cyanuric acid in pools

A chlorinated pool with cyanuric acid will remain chlorinated in direct sunlight; whereas without a stabiliser, chlorine will dissipate and leave the pool unprotected without free chlorine in a matter of hours. Most importantly, cyanuric acid will not be consumed in this helpful work and will, over time, start to build up in pool water.

Cyanuric acid has many extraordinary benefits for the pool industry. It has allowed the typical home owner, HOA [home owners’ association — the US equivalent of a body corporate] and pool service professional to manage a pool’s water chemistry with less effort and with higher consistency. Allowing for weekly water maintenance instead of daily has created an opportunity for service companies to take care of more pools with less hassle and fewer emergency house calls (algae, etc). Overall, the market for cyanuric has exploded, creating a US$300 million a year business. Unfortunately, the misconception of ‘if some is good, more is better’ has perpetuated throughout the industry and could not be further from the truth. Let’s investigate the practical science of why this is the case and why the importance of cyanuric measurement is critical in keeping our pools clean and safe.

Consequences of a high cyanuric acid level

Chlorine’s potential to oxidise, often measured as oxidation-reduction potential (commonly referred to as ORP), is a good indicator of the effectiveness of chlorine to oxidise and sanitise swimming pool water. Over the years, numerous independent and academic research initiatives have shown when cyanuric levels build up in the pool, ORP levels consistently drop, indicating that the effectiveness of chlorine diminishes. In addition, there is a clear correlation to increased levels of cyanuric acid and the time it takes to effectively kill bacteria present in pool water.

The chart below demonstrates the amount of time to kill 99% of bacteria at various levels of cyanuric acid and different levels of chlorine. Taking one example from the data, at cyanuric acid levels of 100 ppm, it takes 20–50 times the amount of time to kill 99% than at 0 ppm of cyanuric acid.

Estimated time (minutes) to kill 99% of bacteria in the presence of cyanic acid.

Image courtesy of Clear Comfort.

Furthermore, at high levels of cyanuric acid, chlorine is rendered ineffective in killing the most dangerous microorganisms in the water: Cryptosporidium parvum.

Effect on Cryptosporidium

Cryptosporidium parvum, or ‘Crypto’ as it is commonly referred to, is a chlorine-resistant microorganism that causes gastrointestinal illness (similar to Giardia) that reproduces in the gut of humans. Crypto has a strong and durable outer shell that allows it to also survive outside of the human body, is spread through drinking water or swimming pool water, and is tolerant to a wide range of chlorine concentrations.

Every year, thousands of documented cases of cryptosporidiosis occur in public swimming pools, mostly originating from faecal matter. When a suspected case of Crypto occurs, the Centers for Disease Control (CDC) recommends that the free chlorine concentration change to 20 ppm for 32 hours to inactivate 99.9% of Crypto in the pool (CT=15,300 mg*min/L). However, the CDC recommendation does not include the level of cyanuric acid that can, and in most cases is, present in outdoor pools.

Recent CDC research presented at the October 2015 World Aquatic Health Conference demonstrates that even at cyanuric acid levels as low as 10–20 ppm, the current recommended remediation protocol is not adequate to inactivate the necessary 99.9% of Crypto in pool water. It also concludes that additional methods and secondary sanitation systems to protect swimmers from faecal accidents are desired.

Moving forward

Responsible training and education on the benefits and misuse of cyanuric acid is critical. Poolside kits that can accurately test for cyanuric acid are available commercially although they are underused or not used at all. Although more people are becoming aware of the consequences of high cyanuric levels, it is still not measured to the degree of other water constituents, like free chlorine.

What happens when your cyanuric acid level is too high? It is simple — the only reliable method to remove cyanuric acid from swimming pools is through draining/dilution or removal through reverse osmosis.

Nick Rancis headshot.

Nick is an accomplished microbiologist with more than 10 years of experience in emerging water technologies, industrial microbiology and commercialisation of public/private ventures. In addition, he is the author of multiple patents and led microbial bio-prospecting expeditions in extreme environments. A frequent speaker in the university technology and start-up accelerator spheres, he is a thought leader in several areas of the water energy nexus and business strategy. He holds a BS in Microbiology from the Colorado State University and is fluent in English and Spanish.

References:

  • Anderson, J. R., “A Study of the Influence of Cyanuric Acid on the Bactericidal Effectiveness of Chlorine”, Amer. Journal of Pub. Health, Oct, 1965.
  • Andersen, J. R., “The influence of cyanuric acid on the bactericidal effectiveness of chlorine,” Ph.D. Dissertation, University of Wisconsin, 1963.
  • Canelli, E., “Chemical, Bacteriological, and Toxicological Properties of Cyanuric Acid and Chlorinated Isocyanurates as Applied to Swimming Pool Disinfection”, Department of Chem., University of Naples, American Journal of Public Health, February, 1974.
  • Fitzgerald, G. P., DerVartanian, M. E., “Pseudomonas aeruginosa for the Evaluation of Swimming Pool Chlorination and Algicides”, Water Chemistry Laboratory, Applied Microbiology, University of Wisconsin, Madison, March, 1969.
  • Hill, V., “Effect of Cyanuric Acid on the Inactivation of Cryptosporidium Parvum Under Hyperchlorination Conditions”. World Aquatic Health Conference. Scottsdale, AZ., Oct, 2015.
  • Johnson, J. D., Disinfection, “Water & Wastewater”, University of North Carolina, Chapel Hill, N.C.
  • Shields JM, Arrowood MJ, Hill VR, Beach MJ. “The effect of cyanuric acid on the chlorine inactivation of Cryptosporidium parvum in 20 ppm free chlorine”, J Water Health, 2009;7(1):109–14.
  • Williams, K., “CYA, Benefactor or Bomb”, Newcastle, CA., Dec, 1997.

Editor’s note: This article was written for the US market and, as such, information pertaining to legislation may differ from Australian law. Please conduct your own research to ensure your facility complies with Australian law.

Image credit: ©Shawn Hempel/Dollar Photo Club

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